fig7

A versatile messenger for chirality communication: asymmetric silica framework

Figure 7. (A) Synthesis of chiral cross-linked polymers of PDVB and PMBA via radical polymerization of divinyl monomers around biphenyl group-bearing SiO2 nanofibers. (B) 13C NMR spectra of L-form Bp-SiO2, DVB@Bp-PEI@SiO2 and isolated PDVB. Solid-state CD and UV-vis absorption spectra of (C) chiral isolated PDVB and (D) TCPP@PDVB. This figure is used with permission from John Wiley and Sons[48]. DVB: Divinylbenzene; MBV: N,N′-methylenebisacrylamide; PDVB: polydivinylbenzene; PMBA: poly(N,N′-methylenebisacrylamide); NMR: nuclear magnetic resonance; CD: circular dichroism; TCPP: tetrakis(4-carboxyphenyl)porphyrin.

Chemical Synthesis
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